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The big clash of the weekend Ronald Koeman entertain his former side as Barcelona take on Valencia at the Camp Nou on Saturday.
The Catalan giants got back to winning ways on Wednesday after humbling surprise leaders Real Sociedad, who travel to Levante later that evening.
Before that, Atletico Madrid have the chance to move top when they host an Elche outfit who have not won in their last six matches.
Real Madrid, meanwhile, are in action on Sunday night against Eibar who are unbeaten in their last five league encounters.
19 December 2020:
Atletico Madrid v Elche
Barcelona v Valencia
Levante v Real Sociedad
Osasuna v Villarreal
Sevilla v Real Valladolid
Celta Vigo v Deportivo Alaves
Granada v Real Betis
Cadiz v Getafe
Eibar v Real Madrid