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Defending champions Real Madrid get the action underway against Huesca in the Spanis capital, with Zinedine Zidane's men looking to build on last week's El Clasico win over FC Barcelona.
The Catalan giants, meanwhile, travel to Deportivo Alves, who they have beaten in their last eight meetings across all competitions.
Elsewhere, Osasuna entertain an Atletico Madrid side looking to extend their winning run to three consecutive matches.
Real Madrid v Huesca
Athletic Club v Sevilla
Osasuna v Atletico Madrid
Deportivo Alaves v Barcelona
Real Betis v Elche
Celta Vigo v Real Sociedad
Granada v Levante
Valencia v Getafe
Villarreal v Real Valladolid
