Juventus 3-1 Sassuolo
Gonzalo Higuain netted a brace for Juventus, as the Serie A Champions recorded a 3-1 win over Sassuolo to move top of the table.
Higuain opened the scoring after four minutes, before he doubled the home side's lead in the 10th minute.
Fellow summer signing, Miralem Pjanic netted Juve's third goal in the 27th minute. While, Luca Antei's 33rd minute strike proved nothing more than a consolation for Sassuolo.
Palermo 0-3 Napoli
Napoli proved too strong for Palermo, as they recorded a 3-0 win at the Stadio Renzo Barbera on Saturday evening.
Marik Hamsik opened the scoring after 47 minutes, before Jose Callejon netted a second-brace to secure Napoli's second win of the season.
The victory moves Napoli up to second in the Serie A standings, two points behind Juventus.