Sevilla 0-2 Getafe
Sevilla's rocky start to the season continued after they went down 2-0 to Getafe on home soil on Sunday evening.
Spanish forward Angel was the hero on the day, as he netted a brace to lead the visitors to their second victory of the season.
Sevilla, meanwhile, have now slumped to second successive defeat in the Spanish top flight.
Real Valladolid 0-1 Deportivo Alaves
Deportivo Alaves needed a 93rd minute goal from Ibai Gómez to snatch a 1-0 win away to Real Valladolid on Sunday evening.
Espanyol 1-0 Levante
Sergio Garcia's 52nd minute strike was enough to hand Espanyol a 1-0 win over Levante at the RCDE Stadium.
Leganes 0-1 Villarreal
Villarreal registered their first win of the season after seeing off Leganes 1-0 at the Estadio Municipal de Butarque.
After Guido Carrillo had missed a penalty for the hosts in the 49th minute, Carlos Bacca scored the winning goal in the 65th minute.